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November 8, 2000
Contact: Tim Stephens (831) 459-2495; stephens@cats.ucsc.edu
INOPERATIVE MERCURY MINES IN THE COAST RANGES FINGERED AS A MAJOR SOURCE OF MERCURY
CONTAMINATION IN CALIFORNIA WATERS
For Immediate Release
SANTA CRUZ, CA--The New Idria mercury mine near Pinnacles National Monument is
one of dozens of inoperative mercury mines in the Coast Ranges of California. It
had one of the longest periods of operation (from 1854 to 1972) and was the second
largest mercury producer in North America. Now, researchers from the University of
California, Santa Cruz, have measured significant amounts of toxic mercury leaching
into a creek that flows past the mine site.
The mercury appears to be coming from the extensive piles of mine tailings on the
site, said Priya Ganguli, lead author of the study, which was published in the current
issue of the journal Environmental Science and Technology. Ganguli, who performed
the research as a graduate student at UCSC, is currently an environmental specialist
with the San Francisco Regional Water Quality Control Board.
The findings have implications far beyond New Idria, said Russell Flegal, professor
and chair of environmental toxicology at UCSC and a coauthor of the study. Preliminary
results from other mine sites indicate that inoperative mercury mines are a major
source of mercury pollution in bodies of water such as San Francisco Bay that consistently
exceed water quality standards for the toxic element, Flegal said. Methylmercury,
the most hazardous form of the element, is a potent neurotoxin that has begun to
receive increased scrutiny from health scientists and regulatory agencies.
"Methylmercury is dangerous because it enters the food chain and accumulates
in fish, which can end up having concentrations of mercury in their tissues a million
times higher than in the surrounding water," Flegal said.
State health officials have issued fish consumption advisories due to mercury pollution
for more than a dozen bodies of water in California, including San Francisco Bay
and several areas in the Coast Ranges.
At the New Idria site, San Carlos Creek is stained bright orange from iron oxides
carried in acidic water that drains out of the mine tunnels. The creek flows northward,
ultimately draining to an area near the Mendota Wildlife Refuge at the headwaters
of the San Joaquin River. Ganguli analyzed mercury concentrations in the acid mine
drainage as well as in samples collected from the creek upstream and downstream from
the mine. The researchers measured total mercury concentrations, as well as the concentrations
of specific forms of mercury, including methylmercury.
"Total mercury concentrations in the acid mine drainage were comparable to concentrations
upstream from the mine, but downstream from the mine there were much higher concentrations,"
Ganguli said. "Based on where the highest concentrations are, we think the primary
source of the mercury is runoff from the mine waste piles alongside the creek."
At New Idria and other California mercury mines, the mercury was extracted from cinnabar
ore in a process called calcination. This involved crushing the ore and roasting
it to release elemental mercury, leaving behind waste rock known as calcine. Invariably,
the calcine waste still contains some soluble mercury that may leach into surface
water and flow into the creek, Ganguli said. Certain types of bacteria convert elemental
mercury (the silvery liquid metal used in thermometers) into methylmercury, although
the conversion can also occur without microbial activity.
The researchers calculated a conservative estimate of 1.5 kilograms (a little over
3 pounds) of mercury entering San Carlos Creek from the New Idria mine each year.
But Ganguli noted that this baseline flux does not account for potentially large
inputs during heavy rains. The annual mercury load from the mine site could be more
than ten times higher than this preliminary estimate, she said.
An important question not answered by this study is how far the mercury travels downstream
from the mine. Studies in other locations have shown that metals from acid mine drainage
can travel hundreds of miles downstream from their source, so it is possible that
some of the mercury from the New Idria mine flows down the San Joaquin River into
San Francisco Bay. But Ganguli said the amount that gets to the bay is probably insignificant
compared to mercury inputs from sources much closer to the bay, such as the New Almaden
mine in the Santa Cruz Mountains near San Jose.
Substantial amounts of mercury are entering the Guadalupe River from the New Almaden
mercury mine, according to Khalil Abu-Saba, a coauthor of the New Idria paper and,
like Ganguli, a former graduate student in Flegal's lab and now an environmental
specialist for the Regional Water Quality Control Board. Abu-Saba, who is working
on regulations to control mercury pollution in San Francisco Bay, said he is convinced
that the New Almaden mine is the biggest ongoing source of mercury in the bay.
In addition to Ganguli, Abu-Saba, and Flegal, the paper's authors include Robert
Mason from the Center for Environmental Studies at the University of Maryland and
Robert Anderson, professor of Earth sciences at UCSC.
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Editor's note: Reporters can contact Ganguli at (510) 622-2427 or pg@rb2.swrcb.ca.gov
and Flegal at (831) 459-2093 or flegal@es.ucsc.edu.
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